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采用四丙基溴化铵（ＴＰＡＢｒ）为模板剂，分别以正丁胺（ＮＢＡ）、己二胺（ＨＤＡ）、二乙胺（ＤＥＡ）、乙二胺（ＥＤＡ）、三丙胺（ＴＰＡ）和四乙基氢氧化铵（ＴＥＡＯＨ）调节凝胶碱度，成功地合成出ＴＳ－１沸石．采用ＩＲ，ＸＲＤ，ＵＶ－Ｖｉｓ和ＮＭＲ等表征技术，详细考察了有机胺的作用及对钛进入沸石骨架的影响．结果表明，以ＴＥＡＯＨ为碱源时抑制钛进入骨架；以ＥＤＡ为碱源时合成的钛硅沸石结晶度低；以ＴＥＡＯＨ或ＮＢＡ为碱源时合成的钛硅沸石晶粒较均匀．有机胺在ＴＳ－１合成过程中只起到调节碱度的作用，未与ＴＰＡＢｒ联合起模板作用．
Using tetrapropylammonium bromide (TPABr) as the template, we used n-butylamine (NBA), hexamethylenediamine (HDA), diethylamine (DEA), ethylenediamine (EDA), tripropylamine (TPA) Tetraethylammonium hydroxide (TEAOH) was used to adjust the gel basicity to synthesize TS-1 zeolite successfully. Using IR, XRD, UV-Vis and NMR characterization techniques, a detailed examination of the role of organic amines and titanium into the zeolite framework. The results show that the use of TEAOH as a source to inhibit the titanium into the framework; EDA as a source of titanium silicate zeolite synthesized low crystallinity; TEAOH or NBA as the source of synthetic titanium silicalite zeolite more uniform. Organic amines in TS-1 synthesis process only play a role in regulating alkalinity, TPABr not combined with the role of the template.