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应用微分反应器,在高空速、小颗粒国产铜锌铝催化剂存在下进行一氧化碳与水蒸汽的反 应,测定了175℃,变换率≤20%,远离平衡下,各组分浓度对反应速率的影响,得到正反应 动力学方程为 还测定了160-210℃之间温度对反应速率的影响,求得温度对反应速率常数的关系;得到反应 的活化能E=6.7×104焦/摩尔,频率因子Z=2.1×106.
The reaction of carbon monoxide with steam in the presence of high-velocity and small-particle domestic Cu-Zn-Al catalyst was carried out by using a differential reactor. The effect of concentration of each component on the reaction rate The kinetic equation of the positive reaction was also obtained. The influence of the temperature between 160-210 ° C. on the reaction rate was also determined, and the relationship between the reaction temperature and the reaction rate constant was obtained. The activation energy E = 6.7 × 104 J / mol, Frequency factor Z = 2.1 × 106.