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本文对芳香醛和酮的锆氢化反应及水解产物进行了研究。产物经NMR证明为相应的醇。并以苯甲醛为代表,初步探讨了锆氢化反应的过程。还研究了含有其他官能团的苯甲醛对锆氢化反应选择性的影响,以及含有较大取代基酮类的锆氢化反应。
In this paper, zirconium hydrides and their hydrolysates of aromatic aldehydes and ketones were studied. The product proved to be the corresponding alcohol by NMR. And benzaldehyde as a representative, preliminary discussion of the zirconium hydrogenation reaction process. The effect of benzaldehyde containing other functional groups on the selectivity of zirconium hydride reaction and the hydrothermal reaction of zirconium with larger substituent ketones were also studied.