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基于胞腔模型和无热溶液理论导出相应的超额热力学函数和液相活度系数方程。同时还给出了由该活度系数方程计算出的14个二元体系的汽液平衡数据,结果是满意的。
The corresponding excess thermodynamic functions and liquidus activity coefficient equations are derived based on the cell model and the solution without solution. At the same time, the vapor-liquid equilibrium data of 14 binary systems calculated from the activity coefficient equation are also given. The results are satisfactory.