Effects of temperature and initial molar ratio of Na_2O to Al_2O_3 on agglomeration of fine Al(OH)_3

• 作 者: 张斌 陈启元 李洁 尹周澜
• 机 构: College of Materials Science and Engineering,Hunan University,School of Chemistry and Chemical Engin
• 出 处: Journal of Central South University of Technology
• 发表日期: 2008年06期
• 关键词: agglomeration OH aluminate Bayer nucleation aggregated disappear batch maintain

Fine Al(OH)3 crystals were aggregated from supersaturated aluminate solution in the batch reaction tanks. By means of laser particle size analyzer and scanning electron microscopy, the influences of temperature and initial molar ratio of Na2O to Al2O3 (αK) on agglomeration of fine seed in Bayer process were investigated. The results show that agglomeration is almost finished in 8 h, and seeds with size less than 2 μm are easily aggregated together, and almost disappear in 8 h under the optimal process conditions. In the aluminate solution with the same moderate initial αK, when the reaction temperature reaches 75 ℃, the secondary nucleation does not occur, and the effect of agglomeration is better. And at the same reaction temperature, when the initial αK is 1.62, the initial supersaturation of aluminate solution is moderate, the binders on the surfaces of the seed are enough to maintain the agglomeration process, and the agglomeration degree is better. From SEM images, agglomeration mainly occurs in the fine particles, the combinations among the fine particles are loose and the new formed coarse crystal shapes are irregular.

Fine Al (OH) 3 crystals were aggregated from supersaturated aluminate solution in the batch reaction tanks. By means of laser particle size analyzer and scanning electron microscopy, the influences of temperature and initial molar ratio of Na2O to Al2O3 (αK) on agglomeration of fine Seed in Bayer process were investigated. The results show that agglomeration is almost finished in 8 h, and seeds with size less than 2 μm are easily aggregated together, and almost disappear in 8 h under the optimal process conditions. same moderate initial αK, when the reaction temperature reaches 75 ° C., the secondary nucleation does not occur, and the effect of agglomeration is better. And at the same reaction temperature, when the initial αK is 1.62, the initial supersaturation of aluminate solution is moderate , the binders on the surfaces of the seed are enough to maintain the agglomeration process, and the agglomeration degree is better. From SEM images, agglomera tion mainly occurs in the fine particles, the combinations among the fine particles are loose and the new formed coarse crystal shapes are irregular.