SYNTHESIS OF BLOCK COPOLYMER FROM 5,6-BENZO-2-METHYLENE-1,3-DIOXEPANE AND METHYL ACRYLATE VIA ATOM T

• 作 者: Jin-ying Yuan Cai-yuan Pan
• 机 构: DepartmentofPolymerScienceandEngineering,DepartmentofPolymerScienceandEngineering
• 出 处: 高分子科学：英文版
• 发表日期: 2002年2期
• 关键词: Atom transfer radical polymerization RING-OPENING polymerization Block copolym
• 基金项目: 国家自然科学基金

Poly(methyl acrylate)-b-poly(5,6-benzo-2-methylene-1,3-dioxepane) (PMA-b-PBMDO) was synthesized by twostep atom transfer radical polymerization (ATRP). Firstly, ATRP of methyl acrylate (MA) was realized using ethyl α-bromobutyrate (EBrB) as initiator in t