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本文从分子轨道理论的角度解释在无机和配位化学中遵循8-32-48电子规则及16-18电子规则的化合物能够稳定存在的原因,此外还讨论了16-18电子规则的一些应用。
In this paper, we explain the reason why compounds that follow the 8-32-48 electron rule and the 16-18 electron rule in inorganic and coordination chemistry can exist stably from the perspective of molecular orbital theory. In addition, some applications of 16-18 electron rule are also discussed.