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通过Friedel-Crafts反应制备了富勒烯化的聚环氧丙基咔唑,聚合物中C60的含量最高可达7.6wt%。通过凝胶渗透色谱法测定了聚合物分子量,并采用1H和13CNMR,IR,热分析及光谱等手段对其结构进行了分析与表征。
Fullerene-based polyepoxypropyl carbazole was prepared by Friedel-Crafts reaction. The content of C60 in the polymer was up to 7.6wt%. The molecular weight of the polymer was determined by gel permeation chromatography. The structure of the polymer was characterized by 1H and 13C NMR, IR, thermal analysis and spectroscopy.