Some Rare Earth Metallic Organohydrides with Biindenyl as the Ligand

• 作 者: GE Yue YUE Zheng-yu GAO Jin-sh
• 机 构: School of Chemistry and Chemical Engineering
• 出 处: 高等学校化学研究（英文版）
• 发表日期: 2004年期
• 关键词: Rare earth metallic hydride Indenyl sodium Synthesis Thermogravimetric analysis

IntroductionIt is well known that organometallic hydrides of rare earth metals are the catalysts and reducing reagents for the catalysis polymerization of alkenes and the catalysis hydrogenation of alkenoalkynes. There are four methods for the syntheses of organometallic hydrides of rare earth metals: (1) the thermal atomization of metals, I. E. , the interaction of a rare earth metal with alkenes with a terminal alkyne; (2) the Ln-C σ bond is broken with H2; (3) metallic hydride replacement[1], I. E., NaBH4, LiA1H4 and Na can be used to react with organometallic compounds of rare earth metals; (4) the elimination ofβ-H, I. E. , in the presence of LiC1, the elimination of theβ-H of the alkyl compounds of rare earth metals gives the target product. The organohydrides of biindenyl samarium, biindenyl gadolinium and biin denyl dysprosium were obtained with NaH reduction method.