THE INFLUENCE OF SUBSTITUENT ELECTRONIC EFFECT ON ETHYLENE OLIGOMERIZATION ACTIVITIES OF BIS(IMINO)P

• 作 者: 李化毅
• 机 构: JointLaboratoryofPolymerScienceandMaterialsKeyLaboratoryofEngineeringPlasticsInstituteofChemistrythe
• 出 处: 高分子科学：英文版
• 发表日期: 2009年5期
• 基金项目: supported by the National Science Foundation of China(Nos20334030,50703044 and 20734002)

Bis(imino)pyridyl Fe(Ⅱ) complexes are important catalysts in ethylene oligomerization for preparingα-olefins. The metal net charge-activity relationship of bis(imino)pyridyl Fe(Ⅱ) complexes was investigated by molecular mechanics (MM) and net charge equil