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Under hydrothermal condition, the reaction of 3-hydroxy-1-adamantaneacetic acid (H2L) with CdCl2 and 1,3-di-4-pyridylpropane (dpp) has afforded a new Cd(Ⅱ) compound, [CdCl(HL)(dpp)(H2O)]n·nH2O (1), which was structurally characterized by single-crystal X-ray diffraction analysis. The crystal is triclinic, space group P1 with a= 1.091 0(1) nm, b=1.131 8(1) nm, c=1.246 4(1) nm, α=88.52(1)°, β=71.34(1)°, γ=68.11(1)°, V=1.345 2(1) nm3, Z=2, Mr=591.40, F(000)=608, Dc=1.460 g·cm-3, μ=0.947 mm-1, the final R=0.040 1 and wR=0.104 0 for 4 950 observed reflections (I>2σ(I)). Complex 1 consists of one-dimensional chains deriving from CdCl(HL)(H2O) units linked by dpp ligands, and lattice water molecules decorate between the chains. The O-H…O and O-H…Cl hydrogen bonds lead to the formation of a 2D layer structure.
Under hydrothermal conditions, the reaction of 3-hydroxy-1-adamantaneacetic acid (H2L) with CdCl2 and 1,3-di-4-pyridylpropane (dpp) has afforded a new Cd (II) compound, [CdCl (H2O)] n · nH2O (1), which was structurally characterized by single-crystal X-ray diffraction analysis. The crystal is triclinic, space group P1 with a = 1.091 0 (1) nm, b = ) nm, c = 1.246 4 (1) nm, α = 88.52 (1) °, β = 71.34 (1) °, γ = 68.11 (1) °, V = 1.345 2 = 591.40, F (000) = 608, Dc = 1.460 g · cm-3, μ = 0.947 mm-1, the final R = 0.040 1 and wR = 0.104 0 for 4 950 observed reflections (I> 2σ (I) . Complex 1 consists of one-dimensional chains deriving from CdCl (HL) (H2O) units linked by dpp ligands, and lattice water molecules decorate between the chains. The OH ... O and OH ... Cl hydrogen bonds leads to the formation of a 2D layer structure.