Synthesis and Crystal Structure of N-[1-(2-Methyl-1-methylcarbamoyl-propylcarbamoyl)-2,3-diphenyl-cy

• 作 者: 潘成学 苏桂发 黄婉云 张勇
• 机 构: College of Chemistry & Chemical Engineering Guangxi Normal University,College of Chemistry & Chemica
• 出 处: 结构化学
• 发表日期: 2008年03期
• 关键词: diphenyl benzamide Methyl intermolecular restricted bonds chains amide orthorhom

N-[1-(2-Methyl-1-methylcarbamoyl-propylcarbamoyl)-2,3-diphenyl-cyclopropyl]-ben-zamide, C29H31N3O3, has been synthesized and characterized by IR, 1H NMR, 13C NMR and single-crystal X-ray diffraction. The crystal is of orthorhombic, space group P212121 with a=11.0855(11), b=18.7756(19), c=24.434(2), V=5085.5(9)3, Z=8, Mr=469.57, Dc=1.227 g/cm3, λ= 0.71070 , μ(MoKα)=0.080 mm-1, F(000)=2000, the final R=0.0579 and wR=0.1111 for 4569 observed reflections with I > 2σ(I). The N-H and oxygen atom are involved in intermolecular hydrogen bonds which link the molecules into a one-dimensional chain.

N- [1- (2-Methyl-1-methylcarbamoyl-propylcarbamoyl) -2,3-diphenyl-cyclopropyl] -benzamide, C29H31N3O3, has been synthesized and characterized by IR, 1H NMR, 13C NMR and single-crystal X -ray diffraction. The crystal is of orthorhombic, space group P212121 with a = 11.0855 (11), b = 18.7756 (19), c = 24.434 (2) , V = 5085.5 (9) 3, Z = 8, Mr = 469.57, Dc = 1.227 g / cm3, λ = 0.71070 μ, μ (MoKα) = 0.080 mm -1, F (000) = 2000, the final R = 0.0579 and wR = 0.1111 for 4569 observed reflections with I> 2σ ( I). The NH and oxygen atom are involved in intermolecular hydrogen bonds which link the molecules into a one-dimensional chain.