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利用固相反应合成了Ｅｕ１－ｘＣａｘＦｅＯ３钙钛矿氧化物．ＸＲＤ测量表明，在ｘ≤０．６范围内为钙钛矿结构；室温下的５７ＦｅＭｏｓｓｂａｕｅｒ谱测试给出３个磁谱和１个顺磁双线谱；在３个磁谱中，１个为处于四配位的Ｆｅ离子，另外２个为处于八配位的Ｆｅ离子．ＸＰＳ谱表明Ｆｅ２ｐ３／２的高结合能端出现与Ｆｅ离子配位状态相对应的肩峰．所有Ｆｅ离子都处于＋３价态．
Eu1-xCaxFeO3 perovskite oxides were synthesized by solid-state reaction. XRD measurements showed a perovskite structure in the x≤0.6 range; 57 FeMossbauer spectroscopy measurements at room temperature gave 3 magnetic spectra and 1 paramagnetic doublet spectrum; of 3 magnetic spectra, 1 was at Four coordination Fe ions, and the other two are eight-coordinated Fe ions. XPS spectra show that the high binding energy of Fe2p3 / 2 shows a shoulder corresponding to the coordination state of Fe ions. All Fe ions are in the +3 valence state.