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前文报道的硫代磷酰二氯在三乙胺存在下与邻苯二酚反应,不仅具有理论意义,而且是合成该类磷化物的新方法。本文将继续报道硫代磷酰一氯以及其它硫代四配位磷化物与邻苯二酚反应的结果,以期进一步揭示这类反应的本质及其影响因素。 1 结果与讨论 当硫代磷酰一氯Ⅰ在三乙胺存在下与邻苯二酚反应时得到六配位磷化物Ⅱ。
The previously reported reaction of thiophosphoryl dichloride with catechol in the presence of triethylamine is not only of theoretical interest but also a new method of synthesizing such phosphides. This article will continue to report the results of the reaction of thiophosphoryl monochloride and other thio-tetra coordination phosphides with catechol in order to further reveal the nature of such reactions and their influencing factors. 1 Results and discussion The hexacoordination phosphide II was obtained when the thiophosphoryl chloride I was reacted with catechol in the presence of triethylamine.