Aqueous-Phase, Palladium-Catalyzed Suzuki Reactions under Mild Conditions

• 作 者: Yueqin Cai Gonghua Song Zhongy
• 机 构: SchoolofChemistryandMolecularEngineering,ShanghaiKeyLaboratoryofChemicalBiology
• 出 处: 绿色与可持续化学(英文)
• 发表日期: 2013年4期
• 关键词: SUZUKI Reaction Ionic Liquid-Supported DIOLS PHOSPHINE-FREE Ligands Suzuki React

Water-soluble ionic liquid-supported diols have been used as phosphine-free ligands in Suzuki couplings of aryl idides/bromides/chlorides under mild conditions in aqueous solvent. It was found that 2,2-bis((1-hexylimidazolium)-mehyl) propane-1,3-diol hexa