Intramolecular substitutions of square planar rhodium(Ⅰ) catioriic complexes of ds-dicarbonyl nitrog

• 作 者: 袁国卿 柳忠阳 朱长城 潘平来 刘世宏
• 机 构: InstituteofChemistry,ChineseAcademyofSciences,Beijing100080,China,China
• 出 处: Science in China(Series B)
• 发表日期: 1997年1期
• 关键词: coordinated complexes planar steric reversible substituted replace aniline borat

Four kinds of square planar cis-dicarbonyl-N,N-bis(2-pyridylethyl)-p-substituted-phenylamino rhodium(Ⅰ) are reported.The changes of their structures were analyzed by XPS,IR and NMR spectroscopy The results show that the weak N→Rh coordinated bond can repl