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The effect of enamel coating on long-term isothermal oxidation at 700 ℃ and cyclic oxidation at 800 ℃ in air and hot corrosion resistance of Ti-24Al-17Nb-0. 5Mo in 75% (Na2SO4 + K2SO4 ) + 25% NaCl (mass fraction) molten mixed salts at 700 ℃ was investigated. The results indicate that Ti-24Al-17Nb-0.5Mo alloy exhibits relatively poor long-term oxidation resistance due to the formation of Al2O3 + TiO2 + Nb2O5 mixed scales and poor hot corrosion resistance due to the spallation of scales formed in molten (Ns, K)2 SO4 +NaCl. Enamel coating can effectively protect Ti-24Al-17Nb-0.5Mo alloy from long-term oxidation at high temperature in air and remarkably improve the hot corrosion resistance of Ti-24Al-17Nb-0. 5Mo alloy, and can act as the barrier to suppress the migration of oxygen and corrosive ions into the substrate.