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对《亚稳态物质φ—pH图》一文中的若干问题做出了进一步阐明:(1)水中固态物(s)的浓度值是由于利用热力学函数ΔGf,i统一讨论同系物多化学反应时的一种自然结果,并不违背化学中对固体物浓度的规定;在当它为非稳定物种时给出一个小于1的浓度数值。(2)绘制水溶物(aq)任意质量摩尔浓度条件下的φ—pH图时,需对水溶物(aq)的DMi函数式再附加一个质量摩尔浓度(m≠1)项。此外,对于用同系物的稳定结构式演绎所得多种情况下的φ—pH图和相关热力学数据的功能特点也作了深入分析。
Several issues in “φ-pH diagram of metastable matter” are further clarified: (1) The concentration of solid in water (s) is due to the use of the thermodynamic function ΔGf, i for a unified discussion of the homologues multi-chemistry A natural result of the reaction does not violate the chemical specification of the solids concentration; it gives a concentration value less than 1 when it is an unsteady species. (2) When plotting φ-pH of aqueous solubles (aq) at any mass concentration, add another mass molar concentration (m ≠ 1) term to the DMi function of water solubles (aq). In addition, the functional characteristics of phi-pH diagrams and related thermodynamic data under various conditions derived from the stable structural formulas of homologues were also analyzed in detail.