【摘 要】
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The method of preparing D-phenylalanine by asymmetric transformation is reported.D-phenylalanine was prepared from DL-phenylalanine by two-step reaction.D-pheny
【机 构】
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Department of Chemistry and Chemical Industry
论文部分内容阅读
The method of preparing D-phenylalanine by asymmetric transformation is reported.D-phenylalanine was prepared from DL-phenylalanine by two-step reaction.D-phenylalanine(2S,3S)-tartrate was prepared by heating DL-phenylalanine, salicylaldehyde,and(2S,3S)-tartaric acid in propionic acid;the obtained D-phenylalanine(2S,3S)-tartrate was treated with triethylamine in ethanol giving D-phenylalanine with 98% optical purity in 69% yield.
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