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报道２，４－Ｂｒ２Ｃ６Ｈ３ＯＣＨ（ＣＮ３）ＣＯ２Ｓｎ（Ｃ６Ｈ１１）２ＣＵ３（１）和２－ＯＣＨ３－４－ＣＨ３ＣＨ＝ＣＨＣ６Ｈ３ＯＣＨ２ＣＯ２Ｓｎ（Ｃ６Ｈ１１）２ＣＨ３（Ｈ２Ｏ）（Ⅱ）的晶体结构和分子结构。（Ⅰ）单斜晶系，空间群Ｐ２１／ｃ，ａ＝１３．０６７（３），ｂ＝１０．５９４（３），ｃ＝１８．１５７（４），β＝１０６．９９（２）°，Ｚ＝４，Ｄｃ＝１．６７２ｇ／ｃｍ３，Ｖ＝２４０３．７３，μ＝４３．７３１ｃｍ－１，Ｍｒ＝６２２．９９，Ｆ（０００）＝１２３２；（Ⅱ）单斜晶系，空间群Ｐ２１／ｎ，ａ＝１０．４０９（１），ｂ＝ １２．５７０（２），ｃ＝２０．６６４（２），β＝８３．５１（１）°，Ｚ＝４，Ｄｃ＝１．２８１ｇ／ｃｍ３，Ｖ＝２６８６．４Ａ３，μ＝９．７６１ｃｍ－１，Ｍｒ＝５３９．２８，Ｆ（０００）＝１１２０．最后的偏离因子，化合物（Ⅰ）Ｒ＝０．０４６，Ｒω＝０．０４６；化合物（Ⅱ）Ｒ＝０．０４９，Ｒω＝０．０４７。晶体结构解析表明，化合物（Ⅰ）和（Ⅱ）中的锡均被配体的３个碳和２个氧原子配位，配位原子呈畸变三角双锥构型；化合物中的环己基均为椅式构象；化合物（Ⅱ）中，配位水分子和另一分子的羰基氧与芳环上的甲基氧?
Reported the crystal structure and molecular structure of 2,4-Br2C6H3OCH (CN3) CO2Sn (C6H11) 2CU3 (1) and 2-OCH3-4-CH3CH = CHC6H3OCH2CO2Sn (C6H11) 2CH3 (H2O) (Ⅰ) Monoclinic, space group P21 / c, a = 13.067 (3), b = 10.594 (3), c = 18.157 , Z = 4, Dc = 1.672g / cm3, V = 2403.73, μ = 43.731cm-1, Mr = 622.99, F (000) = 1232; A = 10.409 (1), b = 12.570 (2), c = 20.664 (2), β = 83.51 (1) °, Z = 4, Dc = 1.281 g /cm3,V=2686.4A3,μ=9.761cm-1,Mr=539.28,F(000)=1120. The last deviation factor, compound (I) R = 0.046, Rω = 0.046; compound (II) R = 0.049, Rω = 0.047. The crystal structure analysis shows that the tin in compounds (I) and (II) is coordinated by three carbon atoms and two oxygen atoms of the ligand, and the coordination atoms are distorted triangular double cones. The cyclohexyl groups in the compounds are Chair conformation; compound (Ⅱ), coordination water molecules and another molecule of carbonyl oxygen and aromatic ring methoxyl?