Regioselective 1,2-Addition of Ti(IV)-enolate to α, β–Unsaturated Compounds

• 出 处: Chinese Chemical Letters
• 发表日期: 2005年05期
• 关键词: carbonyl unsaturated lithium Reich crude silica predominantly ketone applying se

The nucleophilic addition of Ti(IV) enolate derived from methyl aryl ketones to α, β–unsaturated compounds was found to be highly selective to give 1, 2 addition products.

The nucleophilic addition of Ti (IV) enolate derived from methyl aryl ketones to α, β-anobaric compounds was found to be highly selective to give 1, 2 addition products.