THE STRUCTURE OF TETRABUTYLAMMONIUM BIS(1,3-DITHIO-2-THION-CYCLOPENTENE-4, 5-DITHIOLATE)PALLADIUM(Ⅱ)

• 出 处: 结构化学
• 发表日期: 1985年02期
• 关键词: Palladium planar monoclinic dimensions sulfur dithio Patterson thion refinement

Mr=984.05 monoclinic P21/c a=8.474(1),b=14.768(3), c=19.494(3) A,6=96.42(1)0, V=2424.5(7)A3, Z=2, (Mokα)=8.Hem-1, F(000)=1039.91, room temperature. The final R=0.0357 for 2696 independant reflections. The Pd(C3S5)22-ion is nearly planar and the Palladium(Ⅱ)-sulfur coordination polyhedron is square planar with Pd-S distances of 2.315A and 2.311A.

Mr = 984.05 monoclinic P21 / ca = 8.474 (1) b = 14.768 (3) c = 19.494 (3) A 6 = 96.42 (1) 0 V = 2424.5 (7) A3 Z = 2 ) = 8.Hem-1, F (000) = 1039.91, room temperature. The final R = 0.0357 for 2696 independant reflections. The Pd (C3S5) 22-ion is nearly planar and the Palladium square planar with Pd-S distances of 2.315A and 2.311A.