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简要介绍了多齿胺膦金属配合物的设计合成．这些多齿配合物显示了单齿胺或膦金属配合物所不具有的丰富结构类型和特殊催化性质．合成和表征了含有结构类似的双亚胺双膦钌配合物（Ｒ，Ｒ）－３和双胺双膦钌配合物（Ｒ，Ｒ）－４．配合物（Ｒ，Ｒ）－４可作为多种芳香酮不对称氢化的手性催化剂，其光学收率最高达９７％．讨论了钌配合物的催化作用机理．
The design and synthesis of multidentate amine phosphine metal complexes are briefly introduced. These multidentate complexes show the rich structural type and special catalytic properties that monodentate amines or phosphine metal complexes do not possess. Synthesis and characterization of the bis (amine bisphosphine) ruthenium complex (R, R) -3 and the bisamine bisphosphine ruthenium complex (R, R) -4 were studied. The complex (R, R) -4 can be used as a chiral catalyst for the asymmetric hydrogenation of many aromatic ketones with an optical yield of up to 97%. The catalytic mechanism of ruthenium complexes is discussed.