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报道了六个铜 (Ⅱ )配合物 { ([Cu(Ⅱ ) (L1 ) ) ] (ClO4) 1 ,[Cu(Ⅱ ) (L2 ) (H2 O) ] (BF4)2 ,[Cu(Ⅱ ) 2 (L3) 2 (ox) ] [Fe(OH) 2 (H2 O) 4 ] (ClO4) 3[Fe(OH) 2 (H2 O) 4 ) ] (ClO4) ,[Cu(Ⅱ ) 2(L4) 2 (AcO) ] (BF4) 4 ,[Cu(Ⅱ ) 2 (L5 ) 2 (H2 O) ] (ClO4) 2 5 ,and [Cu(Ⅱ ) 2 (L6) (OH) (H2 O) 2 ](BF4) 2 6}的合成和结构 .配合物 1属三斜晶系 ,Pl空间群 ,α=1 1 .1 4 7(6)× 1 0 -1 0 m ,b =1 1 .481 (7)× 1 0 -1 0 m ,c=7.770 (3)× 1 0 -1 0 m ,α=98.81 (4) ,β=1 0 6 .94(4) ,γ =66 .49(4) ,V =871 .5(8)× (1 0 -1 0 m) 3,Z =2 ;配合物 2属单斜晶系 ,P2 1 c空间群 ,α=9.759(2 )× 1 0 -1 0 m ,b=1 4 .449(1 )× 1 0 -1 0 m ,c=1 0 .979(1 )× 1 0 -1 0 m ,β=1 0 1 .0 9(1 ) ,V =1 51 9.(9)× (1 0 -1 0 m) 3,Z =4;配合物 3属正交晶系 ,Fddd空间群 ,α =2 4 .390 (4)× 1 0 -1 0 m ,b =30 30 .538(6)× 1 0 -1 0m ,c=1 8.494(6)× 1 0 -1 0 m ,V =1 3774(5)× (1 0 -1 0 m) 3,Z =8,配合物 4属单斜晶系 ,P2 1 c空间群 ,α=8.47(1 )× 1 0 -1 0 m ,b =2 6 .542 (8)× 1 0 -1 0 m ,c =1 4 .1 0 0 (6)× 1 0 -1 0 m ,β =91 .34(6) ,V =31 64(4)× (1 0 -1 0 m) 3,Z =4,配合?
(CuO) (ClO4) 1, [Cu (II) (L2) (H2O)] (BF4) 2 and [Cu (II) 2 (L3) 2 (ox)] [Fe (OH) 2 (H 2 O) 4] (ClO 4) 3 [Fe (OH) 2 (H 2 O) 4)] ) 2 (AcO)] (BF4) 4 [Cu (II) 2 (L5) 2 (H2O)] (ClO4) ] (BF4) 2 6}. The complex 1 belongs to triclinic system with space group P1, α = 1 1 .1 4 7 (6) × 1 0 -1 0 m, b = 1 1 .481 (7) × 1 0 -1 0 m, c = 7.770 (3) × 1 0 -1 0 m, α = 98.81 (4), β = 1 0 694 (4), γ = 66.49 ), V = 871.5 (8) × (1 0 -1 0 m) 3, Z = 2. The complex 2 belongs to the monoclinic space group P2 1 c with α = 9.759 (2) × 10 ~ 1 0 m, b = 1 4 .449 (1) × 1 0 -1 0 m, c = 1 0 .979 (1) × 1 0 -1 0 m, β = 1 0 1 .0 9 (1), V = 1 51 9. (9) × (1 0 -1 0 m) 3, Z = 4; Complex 3 belongs to the orthorhombic system with Fddd space group, α = 24.390 (4) × 1 0 - 1 0 m, b = 30 30 .538 (6) × 1 0 -1 0m, c = 1 8.494 (6) × 1 0 -1 0 m, V = 1 3774 (5) × (1 0 -1 0 m ) 3, Z = 8, the complex 4 belongs to the monoclinic system, P2 1 c space group, α = 8.47 (1) × 1 0 -1 0 m, b = 2 6 .542 (8) × 1 0 -1 0 m , C = 1 4 .1 0 0 (6) × 1 0 -1 0 m, β = 91.34 (6), V = 31 64 (4) × (1 0 -1 0 m) 3, Z = 4 , With?