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A metal-organic Complex [Cu2(ipt)(Medpq)2]n(ipt=isophthalic acid,Medpq=2-methyldipyrido[3,2-f:2′,3′-h]quinoxaline) 1 has been hydrothermally synthesized and structurally characterized by elemental analysis,IR spectrum,TG and single-crystal X-ray diffraction.Title compound crystallizes in the monoclinic system,space group C2/c,with a=2.389 2(6) nm,b=0.709 60(18) nm,c=1.922 2(5) nm,β=108.655(3),V=3.087 8(14) nm3,C38H24Cu2 N8O4,Mr=783.73,Dc=1.686 g.cm-3,Z=4,the final R=0.055 4 and wR=0.128 5.In the crystal structure,the copper atom is three-coordinated with one carboxylate oxygen atom from carboxylate groups and two nitrogen atoms from Medpq ligand,showing a slightly distorted triangle geometry.Furthermore,it exhibits a zero-dimensional structure with ipt-Cu-medpq as building units.CCDC: 747544.
A metal-organic complex [Cu2 (ipt) (Medpq) 2] n (ipt = isophthalic acid, Medpq = 2-methyldipyrido [3,2- f: 2 ’, 3’-h] quinoxaline) 1 has been hydrothermally synthesized Structurally characterized by elemental analysis, IR spectrum, TG and single-crystal X-ray diffraction. Titanium compound crystallizes in the monoclinic system space group C2 / c with a = 2.389 2 (6) nm, nm = 3, V = 3.087 8 (14) nm3, C38H24Cu2N8O4, Mr = 783.73, Dc = 1.686 g.cm-3, Z = 4, the final R = 0.055 4 and wR = 0.128 5. In the crystal structure, the copper atom is three-coordinated with one carboxylate oxygen atom from carboxylate groups and two nitrogen atoms from Medpq ligand, showing a slightly distorted triangle geometry. Futurerther, it exhibits a zero -dimensional structure with ipt-Cu-medpq as building units. CCDC: 747544.