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The new cadmium(II) coordination polymer [Cd(bte)2(dca)2]n 1 (bte = 1,2-bis(1,2,4- triazol-1-yl)ethane, dca = dicyanamide) was synthesized and characterized by single-crystal X-ray diffraction. The crystal is of monoclinic, space group P21/n with a = 8.7148(15), b = 8.6142(17), c = 15.204(3) A, β = 92.100(10)o, V = 1140.6(4) A3, Z = 2, Mr = 572.87, Dc = 1.668 g/cm3, F(000) = 572, μ = 1.004 mm-1, the final R = 0.0654 and wR = 0.1429 for 1737 observed reflections (I > 2σ(I)). The cadmium atom is coordinated equatorially by four nitrogen atoms from four bte ligands and axially by two nitrogen atoms from two dca anions to adopt a distorted octahedral geometry. Each bte molecule bridges two cadmium(II) atoms. Two strands of bte molecules are wrapped around each other, and held together by cadmium(II) atoms. 1 Forms a double chain structure containing eighteen-membered Cd2(bte)2 rings.
The new cadmium (II) coordination polymer [Cd (bte) 2 (dca) 2] n 1 was synthesized from dte = 1,2-bis and characterized by single-crystal X-ray diffraction. The crystal is of monoclinic space group P21 / n with a = 8.7148 (15), b = 8.6142 (17), c = 15.204 (3) A, ), V = 1140.6 (4) A3, Z = 2, Mr = 572.87, Dc = 1.668 g / cm3, F (000) = 572, μ = 1.004 mm-1, the final R = 0.0654 and wR = 0.1429 for 1737 observed reflections (I> 2σ (I)). The cadmium atom is coordinated equatorially by four nitrogen atoms from four bte ligands and axially by two nitrogen atoms from two dca anions to adopt a distorted octahedral geometry. Each bte molecule bridges two cadmium ( II) atoms. Two strands of bte molecules are wrapped around each other, and held together by cadmium (II) atoms. 1 Forms a double chain structure containing eighteen-membered Cd2 (bte) 2 rings.