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以手性亚磺酰胺作为催化剂,三氯硅烷为还原剂,发展了通过有机小分子催化合成有用的手性β-氨基膦酸酯的方法,获得了较好的产率和对映选择性。
With chiral sulfenamide as catalyst and trichlorosilane as reductant, the method of synthesizing useful chiral β-amino phosphonates by small organic molecules has been developed, and good yields and enantioselectivities were obtained.