硝基苯与正十六烷二元溶液在临界区域的浊度

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测量了硝基苯与正十六烷二元溶液在临界区域不同波长及温度下的浊度,结合与关联长度、渗透压缩系数、共存曲线有关的三个指前因子(X_0,ξ_0,B)的比例关系:R=ξ_0[B~2/(4k_BT_cX_0)]~(1/3)(k_B和T_c分别为玻尔兹曼常数与临界温度)及R的理论值(0.65—0.67),用Ornstein-Zemike方程拟合浊度-温度-波长数据,得到临界指数γ与ν,在误差范围内与理论值一致.将γ与v固定在理论值1.241和0.63,求得ξ_0为0.168nm(R=0.65)和0.174nm(R=0.67),X_0为2.81×10~(-9)m~3·J~(-1)(R=0.65)和2.85×10~(-9)m~3·J~(-1)(R=0.67).
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