N-磺酸基聚(4-乙烯吡啶)硫酸氢铵作为新型、高效、可重复使用的固体酸催化剂用于无溶剂条件下酰化反应(英文)

• 作 者: Nader Ghaffari Khaligh Parisa Ghods Ghasem-Abadi
• 机 构: Department of Chemistry,Qaemshahr Branch,Islamic Azad University,Qaemshahr,47651-61964,Iran,House Re
• 出 处: 催化学报
• 发表日期: 2014年07期
• 关键词: 酰化反应 固体酸催化剂 aldehydes alcohols phenols anhydride readily amines sulfonic anion

N-Sulfonic acid poly(4-vinylpyridinum) hydrogen sulfate has been developed as a recyclable solid acid catalyst for the acetylation of alcohols, phenols, thiols, and amines, as well as the 1,1- diacetylation of aldehydes under solvent-free conditions at room temperature. The acetylated products were formed in good to excellent yields over short reaction times, and the catalyst could be readily recovered by filtration and used several times without any discernible loss in activity. The hydrogen sulfate anion of the catalytic system was found to play a critical role in enhancing the reaction time and yield of the acetylation reaction.

N-Sulfonic acid poly (4-vinylpyridinum) hydrogen sulfate has been developed as a recyclable solid acid catalyst for the acetylation of alcohols, phenols, thiols, and amines, as well as the 1,1-diacetylation of aldehydes under solvent-free conditions at room temperature. The acetylated products were formed in good to excellent yields over short reaction times, and the catalyst could be detected recovered by filtration and used several times without any discernible loss in activity. The hydrogen sulfate anion of the catalytic system was found to play a critical role in enhancing the reaction time and yield of the acetylation reaction.