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本文通过B_nH_n~(2-)(n=10,12)及B_3H_8~-盐分别与C_5H_5FeC_5H_4CH_2N(R)Me_2Cl和Fe(C_5H_4CH_2N(R)Me_2Cl)_2(R=CH_3—,C_2H_5—,n-C_3H_7—,CH_2=CH—CH_2—和CH≡C—CH_2—)在水溶液中进行反应,合成了相应的三十个新的硼烷阴离子衍生物,这些化合物对水稳定性好,B_(10)H_(10)~(2-)及B_(12)H_(12)~(2-)衍生物对热、酸、碱和氧化剂均很稳定。研究了反应物之间的用量比例对反应产物的影响。实验结果表明,不论反应物之间的克分子比如何变化,只能得到相应的一种产物(产率90—98％)。
In this paper, the effects of B_nH_n ~ (2 -) (n = 10,12) and B_3H_8 ~ - salts on the interaction between C_5H_5FeC_5H_4CH_2N (R) Me_2Cl and Fe_ (C_5H_4CH_2N (R) Me_2Cl) _2 (R = CH_3-, C_2H_5-, n_C_3H_7- , CH_2 = CH-CH_2- and CH≡C-CH_2-) were reacted in aqueous solution to synthesize the corresponding thirty new borane anion derivatives. These compounds have good stability against water, B_ (10) H_ 10) ~ (2-) and B 12 (12) H 12 ~ (2-) derivatives are stable to heat, acid, alkali and oxidant. The effect of the amount of reactants on the reaction products was studied. The experimental results show that only one corresponding product can be obtained regardless of the molar ratio of reactants (yield 90-98%).