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在碱性条件下,聚邻二硒代苯被硼氢化钾还原成双硒负离子后与二卤代物缩合关环,得到7个邻苯二硒型硒杂冠醚化合物,其结构经元素分析、MS、IR和~1H NMR证实。
Under alkaline conditions, poly-o-selenobenzene was reduced to double selenium anion by potassium borohydride and then condensed with dihalogenated ring to get 7 o-selenobenzene selenonium selenium compounds. The structure of the compounds was characterized by elemental analysis, MS, IR and ~ 1H NMR confirmed.