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近来,以过渡金属络合物为催化剂,对低温水煤气变换反应(1)进行了许多研究工作。MCO+H_2O(?)CO_2+H_2 (1)尽管化学平衡表明,低温下非常有利于氢化产物的生成(K_(1078k)=1.105,K_(300k)=1.5
Recently, many studies have been carried out on the transition reaction of low-temperature water-gas (1) using transition metal complexes as catalysts. MCO + H_2O (?) CO_2 + H_2 (1) Although the chemical equilibrium indicates that the formation of hydrogenated products is very favorable at low temperature (K 1078k = 1.105 and K 300k 1.5