Synthesis and Structure of One New Metal-organic Framework Based on Flexible Tetrapyridines and Alip

• 作 者: LIU Xi-Hui ZHUO Xin LIU Chao W
• 机 构: SchoolofChemicalEngineering,AnhuiKeyLaboratoryofSpinElectronandNanomaterialsSuzhouUniversity
• 出 处: 结构化学
• 发表日期: 2014年4期
• 关键词: 框架结构 合成 聚羧酸 脂肪族 X-射线单晶衍射 金属 柔性 单斜晶系 crystal structure coordination complex net
• 基金项目: Supported by the Natural Science Foundation of Anhui province Education Department （K.12011Z369, K J2012A268, K J2013B292）, Foundation ofAnhai provincial Education Department for Outstanding Young Tal

One new complex has been produced under solvothermal reactions of tetrakis(4-pyridyloxymethylene)methane(TPOM) with glutaric acid(GA) in the presence of nitrates of cuprum in DMF/H2O(1:5, v/v), namely, {Cu2(TPOM)·GA)2}n. The complex crystallizes in t