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A new inorganic-organic hybrid supramolecular compound [Habo]6[V10O28]? 2C3H7OH?2H2O 1 (abo = R(–)-2-amino-1-butanol) has been synthesized from VO2+ in organic solvents and its crystal structure was reported as follows: monoclinic, space group P21/n, a = 11.419(9), b = 16.811(16), c = 15.521(12) ?, β = 102.98(2)o, V = 2903(4) ?3, Z = 4, C15H46N3O19V5, Mr = 827.25, Dc = 1.893 g/cm3, λ(MoKα) = 0.71073 ?, μ = 1.636 mm-1, F(000) = 1696, the final R = 0.0696 and wR = 0.1361 for 4641 observed reflections with I > 2σ(I). The compound is based on decavanadate clusters [V10O28]6–. The hydrogen bonding interactions among Habo+ cations, solvents and decavanadate clusters extend 1 into a three-dimensional supramolecular architecture.
A new inorganic-organic hybrid supramolecular compound [Habo] 6 [V10O28] • 2C3H7OH • 2H2O 1 (abo = R (-) - 2-amino- 1 -butanol) has been synthesized from VO2 + in organic solvents and its crystal structure was reported as follows: monoclinic, space group P21 / n, a = 11.419 (9), b = 16.811 (16), c = 15.521 (12) Z = 4, C15H46N3O19V5, Mr = 827.25, Dc = 1.893 g / cm3, λ (MoKα) = 0.71073Å, μ = 1.636 mm-1, F (000) = 1696, the final R = 0.0696 and wR = 0.1361 for 4641 at reflections with I> 2σ (I). The compound is based on decavanadate clusters [V10O28] 6-. The hydrogen bonding interactions among Habo + cations, solvents and decavanadate clusters extend 1 into a three-dimensional supramolecular architecture.