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羧酸三环己基锡盐是一类具有生物活性的有机锡化合物,但文献报道得很少.为此,我们系统地研究了三环己基氢氧化锡同羧酸的反应,考察了影响产物收率的因素并合成了23个新的羧酸三环己基锡盐类化合物.通过红外光谱和质谱等确定了这类化合物的结构,证明锡的配合价为4.实验所有有机酸和四氯化锡均为试剂品、氯代环己烷由环己醇经卢卡氏试剂(ZnCl_3-HCl)制
Tricyclohexyltin carboxylate is a class of organotin compounds with biological activity, but few reports have been reported.Therefore, we systematically studied the reaction of tricyclohexyl tin hydroxide with carboxylic acid, And 23 new tricyclohexyl tin carboxylates were synthesized.The structure of these compounds was confirmed by IR and MS.The results showed that the coordination number of tin was 4. Experiment All organic acids and tetrachloride Tin are reagent products, chlorinated cyclohexane from cyclohexanol by Lucca reagent (ZnCl_3-HCl) system