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A strain of photosynthetic bacterium, Rhodopseudomonas palustris W1, isolated from a lab-scale anaerobic moving bed biofilmreactor (MBBR) treating textile effluent was demonstrated to decolodze Reactive Black 5 (RB5) efficiently under anaerobic condition.By a series of batch tests, the suitable conditions for RB5 decolorization were obtained, namely, pH