Syntheses and Structures of Two Ruthenium（Ⅲ） Complexes [Ru（PPh3）2（S2CNR2）Cl2]·CH2Cl2（R=Et and ^

• 作 者: WU Fang-Hui DUAN Tai-Ke LU Lu-
• 机 构: MaterialChemistryLaboratory,InstituteofMolecularEngineeringandAppliedChemistry
• 出 处: 结构化学
• 发表日期: 2010年1期
• 关键词: 单核配合物 二氯甲烷 钌(Ⅲ) 知识产权 膦配体 CL2 体结构 注册商标 ruthenium dithiocarbamate synthesis cry
• 基金项目: This work was supported by the Natural Science Foundation of China and the Programfor New Century Excellent Talents in University （20771003 and NCET-06-0556）

Oxidation reaction of [Ru(PPh3)3Cl2] with tetraethylthiuram disulfide [Et2NCS2]2 or tetra-iso-propylthiuram disulfide [iPr2NCS2]2 afforded ruthenium(Ⅲ) complexes [Ru(PPh3)2(S2CNR2) Cl2]·CH2Cl2(R=Et 1,iPr 2) which were characterized by single-crystal