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Three stable coordination polymers(CPs)assembled by 3,5-(carboxybenzyloxy)-benzoic acid(H3L)and 1,10-phenanthroline(phen),namely,[Zn(HL)(phen)]n(1),[Cd(HL)(phen)]n(2)and[Co(HL)(phen)]n(3),have been synthesized under hydrothermal conditions.Their structure