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It was observed that hydrazine could enhance the chemiluminescence (CL) intensity of tris-(1,10-phenanthroline)ruthenium(Ⅱ)(Ru(phen)_3~ 2+ )- Cerium(Ⅳ) (Ce(Ⅳ)) system, based on which, a novel CL system, Ru(phen)_3~ 2+ -Hydrazine-Ce(Ⅳ), was established. This CL system was investigated and employed to detect hydrazine. Under the optimum experimental conditions, the linear range and detection limit of the proposed method are 2.0×10~ -6 -2.0×10~ -3 g·L~ -1 and 1.8×10~ -6 g·L~ -1 , respectively. For 1.5×10~ -5 , 1.5×10~ -4 and 1.2×10~ -3 g·L~ -1 hydrazine, the relative standard deviation (RSD) is 2.9%, 2.2% and 3.1%, respectively (n=11). The proposed method has been used to detect the content of hydrazine in the synthetic samples with satisfactory results.
It was observed that the hydrazine could enhance the chemiluminescence (CL) intensity of tris- (1,10-phenanthroline) ruthenium (Ⅱ) (Ru (phen) _3 ~ 2+) Based on which, a novel CL system, Ru (phen) _3 ~ 2+ -Hydrazine-Ce (IV), was established. This CL system was investigated and employed to detect hydrazine. Under the optimum experimental conditions, the linear range and detection limit of the proposed method are 2.0 × 10 -6 -6.0 × 10 -3 g · L -1 and 1.8 × 10 -6 g · L -1, respectively. For 1.5 × 10 -5, 1.5 The relative standard deviation (RSD) was 2.9%, 2.2% and 3.1% respectively (n = 11). The proposed method has been used to detect the content of hydrazine in the synthetic samples with satisfactory results.