【摘 要】
:
A series of noble metal catalysts (Ru, Rh, Ir, Pt, and Pd) supported on alumina-stabilized magnesia (Spinel) were used to produce syngas by methane reforming wi
【机 构】
:
Chemical Engineering Department Iran University of Science and Technology,P.O.Box 16315-67,Tehran,Ir
【出 处】
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Journal of Natural Gas Chemistry
论文部分内容阅读
A series of noble metal catalysts (Ru, Rh, Ir, Pt, and Pd) supported on alumina-stabilized magnesia (Spinel) were used to produce syngas by methane reforming with carbon dioxide. The synthesized catalysts were characterized using BET, TPR, TPO, TPH, and H2S chemisorption techniques. The activity results showed high activity and stability for the Ru and Rh catalysts. The TPO and TPH analyses indicated that the main reason for lower activity and stability of the Pd catalyst was the formation of the less reactive deposited carbon and sintering of the catalyst.
The series of noble metals catalysts (Ru, Rh, Ir, Pt, and Pd) supported on alumina-stabilized magnesia (Spinel) were used to produce syngas by methane reforming with carbon dioxide. The synthesized catalysts were characterized using BET, TPR, TPO The activity results showed high activity and stability for the Ru and Rh catalysts. The TPO and TPH analyzes indicated that the main reason for lower activity and stability of the Pd catalyst was the formation of the less reactive deposited carbon and sintering of the catalyst.
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