New Chiral Metal Cluster Systems for Catalytic Asymmetric Syntheses of Chiral Alcohols

• 作 者: LIYan-yun CHENJian-shan YANGCh
• 机 构: DepartmentofChemistry,GraduateSchoolofScienceandEngineering
• 出 处: 高等学校化学研究：英文版
• 发表日期: 2004年2期
• 关键词: 手性 金属聚类系统 芳族酮 不均匀传输催化 Ru3(CO)12 Chiral cluster systems Asymmetric transfer hydr
• 基金项目: Supported by the National Natural Science Foundation of China(No.2 0 0 730 34,2 0 3730 5 6,2 0 1710 37),Fujian Provinceand Technology Comm ission(No.2 0 0 2 F0 16 ) and Xiamen Science and Technology C

The efficient chiral Ru3(CO)12 systems were prepared in situ from Ru3(CO)12 and various chiral diiminoor diamino-diphosphine tetradentate ligands. The systems have been used for the asymmetric transfer hydrogenation of propiophenone in 2-propanol, leading