【摘 要】
：
The title compound [Cu(Phen)3](ClO4)2(btio)(H2O), where btio=2-(4'benzoyloxyl)-4,4,5,5-tetramethylimidazoline-l-oxyl-3-oxide, has been prepared and structurally
【机 构】
：
Science of College,Department of Chemistry, State Key Laboratory of Coordination Chemistry
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The title compound [Cu(Phen)3](ClO4)2(btio)(H2O), where btio=2-(4'benzoyloxyl)-4,4,5,5-tetramethylimidazoline-l-oxyl-3-oxide, has been prepared and structurally characterized by X-ray diffraction. It crystallizes in triclinic, space group P1 with a=13.049(4), b=13.827(5), c=14.860(5) A, α=71.736(6),β=77.076(6), y= 87.054(6)°, C5oH43Cl2CuN8O13, Mr=1098.36, V=2481(1) A3, Z=2, Dc=1.470 g/cm3, μ(MoKα)=0.622 mm-1, F(000)=1132, the final R=0.0639 and wR=0.1473 for 8705 independent reflections with Rint =0.0285. The title compound is composed of [Cu(Phen)3]2+ moiety, one btio, two perchlorate ions and one water molecule. The copper(Ⅱ) ion is octahedrally coordinated by three 1,10-phenanthroline ligands. The outer sphere consisting of one btio, two perchlorate ions and one water molecule is combined with the inner by hydrogen bonds and electrostatic interactions.
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