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采用水热法合成了二维配位聚合物[Pb(suc)0.5(phen)2]2n.2nNO3(H2suc=丁二酸,phen=1,10-邻菲啰啉).对其进行了元素分析、红外光谱表征和X射线单晶衍射测定.该配合物属于三斜晶系,空间群P-1,晶胞参数a=9.0618(17),b=11.533(2),c=11.963(2),α=96.404(2),β=109.720(2),γ=100.842(2),°V=1135.0(3)3,C52H36Pb2N10O10,Mr=1375.29,Dc=2.012 g/cm3,μ(MoKα)=7.484 mm-1,F(000)=662,Z=1,R1=0.0248,wR2=0.0630.
Two-dimensional coordination polymers [Pb (suc) 0.5 (phen) 2] 2n.2nNO3 (H2suc = succinic acid and phen = 1,10-phenanthroline) were synthesized by hydrothermal method. The complex belongs to the triclinic system with space group P-1, the unit cell parameters a = 9.0618 (17), b = 11.533 (2), c = 11.963 (2) , α = 96.404 (2), β = 109.720 (2), γ = 100.842 (2), ° V = 1135.0 (3) 3, C52H36Pb2N10O10, Mr = 1375.29, Dc = 2.012 g / cm3, 7.484 mm-1, F (000) = 662, Z = 1, R1 = 0.0248, wR2 = 0.0630.