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Three coordination polymers based on the V-shaped 4,4’-dicarboxybiphenyl sulfone (H2sdba) ligands, [Zn3(μ-OH)2(sdba)2]n·2nH2O 1, [Zn2(sdba)2(4,4’-bipy)]n·2nH2O 2 and [Zn3(sdba)3(py)2]n·n(py)·nH2O 3 (4,4’-bipy = 4,4’-bipydine), were hydrothermally synthesized and structurally characterized. Complex 1 features the 2D planes constructed by the sdba ligands linking infinite Zn-O-C SBUs. The 4,4’-bipy ligands in 2 bridge the ZnII-sdba chains into interpenetrated 2D planes. The 3D network of α-Po topology in 3 is built from tri-nuclear Zn3 units with a [Zn3(OOC)6] structure. The intense blue and yellow luminescence was observed in complexes 1～3 which may result from ligand-to-metal charge transfer (LMCT).
Three coordination polymers based on the V-shaped 4,4’-dicarboxybiphenyl sulfone (H2sdba) ligands [Zn3 (μ-OH) 2 (sdba) 2] n · 2nH2O 1, -bipy) n · 2nH 2 O 2 and [Zn 3 (sdba) 3 (py) 2] n · n (py) · nH 2 O 3 (4,4’-bipy = 4,4’-bipydine) were hydrothermally synthesized and structurally characterized. Complex 1 features the 2D planes constructed by the sdba ligands linking infinite Zn-OC SBUs. The 4,4’-bipy ligands in 2 bridge the ZnII-sdba chains inter interpenetrated 2D planes. The 3D network of α-Po topology in 3 is built from tri-nuclear Zn3 units with a [Zn3 (OOC) 6] structure. The intense blue and yellow luminescence was observed in complexes 1 ~ 3 which may result from ligand-to-metal charge transfer (LMCT).