N-邻羟苄亚基苯胺Schiff碱铜配合物的合成、结构和性能表征(英文)

• 作 者: 建方方 李琳 孙萍萍 肖海连
• 机 构: 青岛科技大学新材料与功能配合物实验室,青岛科技大学新材料与功能配合物实验室,青岛科技大学新材料与功能配合物实验室,青岛科技大学新材料与功能配合物实验室 青岛266042,青岛266042,青岛2660
• 出 处: 无机化学学报
• 发表日期: 2004年11期
• 关键词: Schiff碱 铜配合物 晶体结构 TG aniline benzoate planar yielding Elmer

The structure of the title compound has been determined by X-ray crystallography. Each copper atom is chelated by two N-salicylidene-aniline anion ligands with Cu-O and Cu-N distances of 0.187 6(3) and 0.200 1(4) nm, respectively. The central copper(Ⅱ) is four-coordinated and in distorted square-planar environment. The phenyl rings with salicylidene moieties form a dihedral angle of 65.40°. There are C-H...e supramolecular interactions in the crystal structure. The title compound is also examined by elemental analysis, FT-IR, UV spectra and TG-DSC analysis. CCDC: 222315.

Each of the copper atoms is chelated by two N-salicylidene-aniline anion ligands with Cu-O and Cu-N distances of 0.187 6 (3) and 0.200 1 (4) The central copper (Ⅱ) is four-coordinated and in distorted square-planar environment. The phenyl rings with salicylidene moieties form a dihedral angle of 65.40 °. There are CH ... e supramolecular interactions in the crystal structure. The title compound is also examined by elemental analysis, FT-IR, UV spectra and TG-DSC analysis. CCDC: 222315.