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不带电荷的含硫醇配体的Cu(Ⅰ)和Ag(Ⅰ)的络合物[CuSR]_n和[AgSR]_n常常是不溶解的高聚物。已经研究过的有限聚合度n的银的络合物[AgSR]_n为数不多。如[AgSC_6H_(11)]_(12)和[AgSCMeEt_2]_8的结构已被测定。铜的化合物[CuSR]_n则研究得更少。kestrn用沸点升高法测定分子量结果表明[AgSR]_n的聚合度η与硫醇的α碳上支链大小有关。本文作者之一与纽约州立大学Albany分校的E. Block和J. Zubieta等人合作,用一类新的α碳
Uncharged mercaptan-containing complexes of Cu (I) and Ag (I) [CuSR] _n and [AgSR] _n are often insoluble polymers. A few silver complexes [AgSR] _n that have been studied have a finite degree of polymerization n. The structures of [AgSC_6H_ (11)] _ (12) and [AgSCMeEt_2] _8 have been determined. Copper compounds [CuSR] _n are studied less. kestrn Determination of molecular weight by boiling point increase The results show that [AgSR] _n degree of polymerization n and thiol α carbon on the branch size. One of the authors, in collaboration with E. Block and J. Zubieta, at the University of New York at Albany, used a new class of alpha carbon