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本文首先对二氯二茂钛(CP_2TiCl_2,CP=环戊=烯基)的合成方法作了评选,找到了一种操作方便、步骤简单且收率高的方法:然后用 CP_2 TiCl_2和某些芳香醇反应合成了化合物 CP_2 Ti(OCH_2C_6H_5)Cl,CP_2Ti〔OCH(CH_3)C_6 H_5〕Cl 和 CP_2 Ti(OCH_2CH_2C_6H_5)Cl,这三个化合物至今未见报道.并且对这些化合物与亲电试剂氯化氢、乙酰氯或苯甲酰氯和亚硫酰氯的反应进行了研究.在其性能研究中,还发现这三个化合物能够强烈地与某些气态给电子配位体如水、甲醇、乙醇、叔丁醇和四氢呋喃等作用,结果使化合物的状态,颜色和组成等都发生明显变化.
In this paper, the synthesis method of dichlorothiocene (CP_2TiCl_2, CP = cyclopentane = alkenyl) was first selected, and a convenient, simple and high yield method was found. Then, CP_2TiCl_2 and some aromatic (OCH_2C_6H_5) Cl, CP_2Ti 〔OCH (CH_3) C_6H_5〕 Cl and CP_2Ti (OCH_2CH_2C_6H_5) Cl have not been reported up to now and these compounds have been reported to react with hydrogen chloride, Acid chloride or benzoyl chloride and thionyl chloride in the study of its performance, also found that these three compounds can be strongly with some of the gaseous electron donor ligands such as water, methanol, ethanol, tert-butanol and tetrahydrofuran and so on Role, the result of the compound state, color and composition have changed significantly.