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Underhydrothermalconditionsthereactionofcis-aconiticacidwithCu2(OH)2CO3andbipy(bipy=2,2?bipy)inH2O/DMF(3:2)affordedaneutralmononuclearcompound[Cu-(bipy)(m2-CO3)(H2O)]2H2O,whichhasbeenstructurallycharacterizedbysingle-crystalX-raydiffractionanalysis.Thecrystalbelongstotriclinic,spacegroupPwitha=8.3950(5),b=8.7974(5),c=9.4496(3),a=98.270(3),b=93.014(3),g=100.068(3),V=677.83(6)3,Dc=1.635g/cm3,Z=2,C11H14CuN2O6,Mr=333.78,m=1.637mm-1,l(MoKa)=0.71073,F(000)=342,thefinalR=0.0616andwR=0.1273for1621observedreflectionswithI>2s(I).Thestructureofthecomplexcontainsadistortedsquarepyramidalcorewithabipy,acarbonateanionandawatermoleculecoordinatingtoaCuⅡatom.ThedihedralanglebetweenthetwoplanescomposedofN(1)N(2)Cu(1)andO(1)O(3)Cu(1)is21.73(8).Theintermolecularhydrogenbonds(O…O)areobservedinthecrystalstructure.
Underhydrothermalconditionsthereactionofcis-aconiticacidwithCu2 (OH) 2CO3andbipy (bipy = 2,2? Bipy) inH2O / DMF (3: 2) affordedaneutralmononuclearcompound [Cu- (bipy) (m2-CO3) (H2O)] 2H2O, whichhasbeenstructurallycharacterizedbysingle-crystalX- raydiffractionanalysis.Thecrystalbelongstotriclinic, spacegroupPwitha = 8.3950 (5) b = 8.7974 (5) c = 9.4496 (3) a = 98.270 (3) b = 93.014 (3) g = 100.068 (3) V = 677.83 (6) D = 1.635g / cm3, Z = 2, C11H14CuN2O6, Mr = 333.78, m = 1.637mm- 1, l (MoKa) = 0.71073, F (000) = 342, thefinalR = 0.0616andwR = 0.1273for1621observedreflectionswithI> 2s (I) . Thestructure of the complex tetxadistants of the dipyridamole core ofhabhabipy, acarbonateanionandawatermoleculecoordinatingtoaCuIIatom.ThedihedralanglebetweenthetwoplanescomposedofN (1) N (2) Cu (1) andO (1) O (3) Cu (1) is21.73 (8) .Theintermolecularhydrogenbonds (O ... O) areobservedinthecrystaltructure.