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分子中被若干个o键隔开的轨道之间存在两种相互作用——通过键的相互作用(TBI)和通过空间的相互作用(TSD).根据这两种作用的分析,我们提出一种综合模型(TBI—TSI相关模型)用以说明有机反应的立体选择性和反应活性.由这一模型推测的结果与许多有机反应的实验事实相符.
There are two kinds of interactions between the orbits separated by several o-bonds in the molecule - the bond interaction (TBI) and the space interaction (TSD) .According to the analysis of these two effects, we propose a The integrated model (TBI-TSI correlation model) is used to illustrate the stereoselectivity and reactivity of the organic reaction The results speculated by this model are consistent with the experimental facts of many organic reactions.