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The complex {[Mn(H2O)4(3, 3?azpy)](3, 3?azpy)3(PF6)2}n (3, 3?azpy = 3, 3? azobispyridine) has been synthesized and characterized. The crystal (C40H40F12MnN16O4P2, Mr = 1153.76) belongs to the triclinic system, space group P with the following crystallographic parameters: a = 10.761(2), b = 11.040(2), c = 23.365(4) ? a = 85.52(1), b = 82.69(1), g = 70.44(1)? V = 2592.5(8) 3, Dc = 1.478 g/cm3, m(MoKa) = 4.16 cm-1, F(000) = 1174, Z = 2, final R = 0.0493 and wR = 0.1158 for the observed reflections (I > 2.00s(I)). The X-ray analysis revealed that manganese(Ⅱ) cation coordination environment is a distorted octahedral geometry, and the Mn2+ cation is coordinated by four oxygen atoms of water in the equatorial plane, while the two nitrogen atoms of 3, 3?azpy occupy the axial positions. The complex forms a one-dimensional chain structure via 3, 3?azpy bridging ligand.
The complex {[Mn (H2O) 4 (3,3? Azpy)] (3,3? Azpy) 3 (PF6) 2} n (3, 3? Azpy = 3, 3? Azobispyridine) has been synthesized and characterized. The crystal (C40H40F12MnN16O4P2, Mr = 1153.76) belongs to the triclinic system, space group P with the following crystallographic parameters: a = 10.761 (2), b = 11.040 (2), c = 23.365 (m) = 4.16 cm-1, F (000) = 1174, Z = 82.69, g = 70.44 1 V = 2592.5 8, Dc = 1.478 g / cm3, 2, final R = 0.0493 and wR = 0.1158 for the observed reflections (I> 2.00s (I)). The X-ray analysis revealed that manganese (II) cation coordination environment is a distorted octahedral geometry, and the Mn2 + cation are coordinated by four oxygen atoms of water in the equatorial plane, while the two nitrogen atoms of 3, 3? azpy occupy the axial positions. The complex forms a one-dimensional chain structure via 3, 3? azpy bridging ligand.